INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY

ASSANE  TOURE; LIBASSE  DIOP

doi:10.29081/jesr.v23i1.91

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Published: Mar 17, 2017

DOI: https://doi.org/10.29081/jesr.v23i1.91

Keywords:

complexes and adduct, discrete structures, mono- and bidentate benzoate, monochelating and monodentate, monochelating benzoate, monochelating or only hydrogen bonding involved salycilate

ASSANE TOURE

Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal

LIBASSE DIOP

Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal

Abstract

The interactions of benzoic or salycilic acids salts with di-, trihalides or SnPh3OH have yielded four new complexes and adducts studied by infrared.The suggested structures are discrete or of infinite chain type, the anion behaving as monodentate and hydrogen bonding involved, or bidentate, the environments around the metallic centres being tetrahedral, octahedral or trigonal bipyramidal. When N-H groups are involved in extra hydrogen bonding, a supramolecular architecture may be obtained.

How to Cite

TOURE, A., & DIOP, L. (2017). INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY. Journal of Engineering Studies and Research, 23(1), 42-45. https://doi.org/10.29081/jesr.v23i1.91

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Vol. 23 No. 1 (2017)

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