INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY

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DAME SEYE
ASSANE TOURE
CHEIKH ABDOUL KHADIR DIOP
LIBASSE DIOP

Abstract

On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained.

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How to Cite
SEYE, D., TOURE, A., DIOP, C. A. K., & DIOP, L. (2020). INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY. Journal of Engineering Studies and Research, 26(3), 69-74. https://doi.org/10.29081/jesr.v26i3.208
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Author Biographies

DAME SEYE

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, Dakar, Senegal

ASSANE TOURE

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, Dakar, Senegal

CHEIKH ABDOUL KHADIR DIOP

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, Dakar, Senegal

LIBASSE DIOP

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, Dakar, Senegal

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