NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY

MAMADOU  NDIAYE; ABDOULAYE  SAMB; LIBASSE  DIOP

doi:10.29081/jesr.v23i3.77

Full text (PDF)

Published: Sep 28, 2017

DOI: https://doi.org/10.29081/jesr.v23i3.77

Keywords:

fullerene, dimeric or infinite chain structures, hydrogen bonds, monochelating ligand, octahedral or square planar environments

MAMADOU NDIAYE

University Cheikh Anta Diop, Dakar, Senegal, Faculty of Sciences and Technics, Department of Chemistry, Laboratory of Natural Products (L.P.N)

ABDOULAYE SAMB

University Cheikh Anta Diop, Dakar, Senegal, Faculty of Sciences and Technics, Department of Chemistry, Laboratory of Natural Products (L.P.N)

LIBASSE DIOP

University Cheikh Anta Diop, Dakar, Senegal, Faculty of Sciences and Technics, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry (LA.CHI.MI.A)

Abstract

On allowing DABCOH2(HC2O4)2 to react with transition metal dihalides in ethanol, a new series of complexes of general formula M(oxalate)2 DABCOH22+. nDABCOH22+.2X- (n=1/2;1) have been obtained. When (n=1) a dimeric structure is suggested, the two monomeric species being hold together by biprotonated DABCO through N-H…O hydrogen bonds. In the case of the complex M(oxalate)2DABCOH22+ .1/2 DABCOH22+.2X- -M = Ni, Cu- the structure is an infinite chain. The environment around the metallic centers is octahedral or square pyramidal. The oxalate behaves as a monochelating and hydrogen bonds involved ligand or is only concerned by hydrogen bonds.

How to Cite

NDIAYE, M., SAMB, A., & DIOP, L. (2017). NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY. Journal of Engineering Studies and Research, 23(3), 26-31. https://doi.org/10.29081/jesr.v23i3.77

Issue

Vol. 23 No. 3 (2017)

Section

Articles

Most read articles by the same author(s)

DAME SEYE, ASSANE TOURE, CHEIKH ABDOUL KHADIR DIOP, LIBASSE DIOP, INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY , Journal of Engineering Studies and Research: Vol. 26 No. 3 (2020): Journal of Engineering Studies and Research
MODOU SARR, AMINATA DIASSE-SARR, LIBASSE DIOP, SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS , Journal of Engineering Studies and Research: Vol. 26 No. 3 (2020): Journal of Engineering Studies and Research
AÏSSATOU GUEYE, MOUHAMADOU BIRAME DIOP, LIBASSE DIOP, NEW PYRIDINE-3-SULFONATO TIN (IV), ANTIMONY (III) AND (V) HALO ADDUCTS AND COMPLEXES: SYNTHESIS AND INFRARED STUDY , Journal of Engineering Studies and Research: Vol. 25 No. 1 (2019): Journal of Engineering Studies and Research
MOUHAMADOU BIRAME DIOP, MODOU SARR, LIBASSE DIOP, ALLEN G. OLIVER, DAVID HUGHES, DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION , Journal of Engineering Studies and Research: Vol. 27 No. 3 (2021): Journal of Engineering Studies and Research
SEYDOU BASSENE, MOUHAMADOU SEMBENE BOYE, MAMADOU SIDIBE, LIBASSE DIOP, CARBOXYLATO ADDUCTS AND DERIVATIVES CONTAINING SnR3 (R = Ph, Me) AND SnMe2 RESIDUES: SYNTHESIS, INFRARED AND MÖSSBAUER STUDIES , Journal of Engineering Studies and Research: Vol. 25 No. 3 (2019): Journal of Engineering Studies and Research
DAME SEYE, CHEIKH ABDOUL KHADIR DIOP, ASSANE TOURE , LIBASSE DIOP, NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY , Journal of Engineering Studies and Research: Vol. 24 No. 1 (2018): Journal of Engineering Studies and Research
MOUHAMADOU SEMBENE BOYE, AMINATA DIASSE-SARR, LIBASSE DIOP, SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES , Journal of Engineering Studies and Research: Vol. 26 No. 2 (2020): Journal of Engineering Studies and Research
MAMADOU NDIAYE, ABDOULAYE SAMB, LIBASSE DIOP, NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY , Journal of Engineering Studies and Research: Vol. 23 No. 3 (2017)
ASSANE TOURE, LIBASSE DIOP, INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY , Journal of Engineering Studies and Research: Vol. 23 No. 1 (2017)
MOUHAMADOU SEMBENE BOYE, MOUHAMADOU BIRAME DIOP, MODOU SARR, AMINATA DIASSE-SARR, LIBASSE DIOP, ALAIN WATTIAUX, SYNTHESIS AND CHARACTERIZATION BY INFRARED AND MOSSBAUER SPECTROSCOPIES OF SOME NEW SnR2 (R = Me, Ph, Bu) RESIDUE CONTAINING ARBOXYALKYLPHOSPHONATE ADDUCTS AND DERIVATIVES , Journal of Engineering Studies and Research: Vol. 29 No. 1 (2023): Journal of Engineering Studies and Research

1 2 > >>

Article Sidebar

Main Article Content

Abstract

Article Details

Most read articles by the same author(s)