CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n

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Published: Jul 27, 2020
DOI: https://doi.org/10.29081/jesr.v26i3.226
Keywords:
infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin

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MODOU SARR
MOUHAMADOU BIRAME DIOP
AMINATA DIASSE-SARR
AI WANG
ULLRICH ENGLERT

Abstract

The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement.

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How to Cite
SARR, M., DIOP, M. B., DIASSE-SARR, A., WANG, A., & ENGLERT, U. (2020). CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n. Journal of Engineering Studies and Research, 26(3), 212-217. https://doi.org/10.29081/jesr.v26i3.226
Issue
Vol. 26 No. 3 (2020): Journal of Engineering Studies and Research
Section
Articles
Author Biographies

MODOU SARR

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Inorganic and Analytical Chemistry Laboratory, Dakar, Senegal

MOUHAMADOU BIRAME DIOP

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Inorganic and Analytical Chemistry Laboratory, Dakar, Senegal

AMINATA DIASSE-SARR

Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Inorganic and Analytical Chemistry Laboratory, Dakar, Senegal

AI WANG

Institute of Inorganic Chemistry, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany

ULLRICH ENGLERT

Institute of Inorganic Chemistry, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany