NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES

Authors

  • WALY DIALLO Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
  • LIBASSE DIOP Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal

DOI:

https://doi.org/10.29081/jesr.v23i2.81

Keywords:

bridging anion, derivatives, supramolecular architectures, trans trigonal bipyramidal environment, triorganotin (IV) residues

Abstract

Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained.

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Published

2017-06-20

Issue

Vol. 23 No. 2 (2017)

Section

Articles

How to Cite

NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES. (2017). Journal of Engineering Studies and Research, 23(2), 12-15. https://doi.org/10.29081/jesr.v23i2.81

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