SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
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Abstract
The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggested, the hydrogenoxolate anion behaving as a monocoordinating or a monochelating ligand. In two studied adducts, supramolecular architectures may be obtained when extra hydrogen bonds involving the free NH groups are considered.
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How to Cite
BOYE, M. S., DIASSE-SARR, A., & DIOP, L. (2020). SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES. Journal of Engineering Studies and Research, 26(2), 15-19. https://doi.org/10.29081/jesr.v26i2.172
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